The man didn't make a move, while considering his options; he hadn't even uttered a single word even while held at gunpoint.
Toxic didn't seem to like this fact, knowing all too well that the man was likely considering his options now, given that he just didn't surrender right away. He was probably even thinking something along the lines of, "Oh, she's not so scary," compared to Z or the others. Maybe he was even belittling her because she was a woman.